Characterization of organic composition in snow and surface waters in the Athabasca Oil Sands Region, using ultrahigh resolution Fourier transform mass spectrometry

Yi, Y and Birks, S.J. and Cho, S. and Gibson, J.J. (2015) Characterization of organic composition in snow and surface waters in the Athabasca Oil Sands Region, using ultrahigh resolution Fourier transform mass spectrometry. Science of The Total Environment, 518-51. pp. 148-158. DOI: https://doi.org/10.1016/j.scitotenv.2015.02.018

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Official URL: http://doi.org/10.1016/j.scitotenv.2015.02.018

Abstract

This study was conducted to characterize the composition of dissolved organic compounds present in snow and surface waters in the Athabasca Oil Sands Region (AOSR) with the goal of identifying whether atmospherically-derived organic compounds present in snow are a significant contributor to the compounds detected in surface waters (i.e., rivers and lakes). We used electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICR MS) to characterize the dissolved organic compound compositions of snow and surface water samples. The organic profiles obtained for the snow samples show compositional differences between samples from near-field sites (<5 km from oil sands activities) and those from more distant locations (i.e., far-field sites). There are also significant compositional differences between samples collected in near-field sites and surface water samples in the AOSR. The composition of dissolved organic compounds at the upstream Athabasca River site (i.e., Athabasca River at Athabasca) is found to be different from samples obtained from downstream sites in the vicinity of oil sands operations (i.e., Athabasca River at Fort McMurray and Athabasca River at Firebag confluence). The upstream Athabasca River sites tended to share some compositional similarities with far-field snow deposition, while the downstream Athabasca River sites are more similar to local lakes and tributaries. This contrast likely indicates the relative role of regional snowmelt contributions to the Athabasca River vs inputs from local catchments in the reach downstream of Fort McMurray.

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Item Type: Article
Uncontrolled Keywords: Athabasca Oil Sands Region; Dissolved organic composition; ESI-FTICR MS; Snow; Surface water
Subjects: Methodology > Other-additional study
Region > Canada > Alberta
Inducing technology > Unconventional hydrocarbon extraction
Inducing technology > Other inducing technology types
Project: SHEER project